Friday chemical safety round-up
Chemical health and safety news from the past week:
- A former chemical hygiene officer guest-posted at ChemistryBlog and answered questions on Reddit
- Also via ChemistryBlog and Reddit, the marvel of a Sigma-Aldrich vending machine for NMR supplies. A robotic tray moves to the correct shelf to catch purchases.
- Chemjobber posted about the importance of a “Chembuddy” in troubleshooting process problems: “People with different and perhaps broader experiences may be able to see beyond the subtle processing effects that are too familiar for others to recognize.” I think the same could likely be said for doing risk assessments.
- CJ also commented on lab traffic flow problems. I’ll add that people trying to get through tight, narrow spaces with essential equipment are probably likely spill more stuff.
- Balancing security and right to know: Plan to publicize hazard information sparks new terrorism concerns
- The National Research Council released its report on “The use and storage of methyl isocyanate (MIC) at Bayer CropScience,” finding that:
Bayer CropScience sought to reduce risks associated with the manufacturing and storage of the toxic chemical methyl isocyanate (MIC) at its processing plant in Institute, W.Va., says a new congressionally mandated report from the National Research Council. However, the company did not make an effort to incorporate all possible hazard control methods, and the report found that not all chemical manufacturing plants have adopted safer processes that aim to minimize or eliminate hazards.
- A French court found Monsanto guilty of chemical poisoning of a farmer, who argued that the company did not provide adequate warnings on the product label of its Lasso herbicide
- EPA fined Syngenta $102,000 “for mislabeling pesticides at facilities in Nebraska and Missouri”
Fires and explosions:
- Two Australian high school students were burned when a crucible exploded while being heated on a Bunsen burner
Leaks, spills, and other exposures:
- When a roofer fell into a vat of 40-70% nitric acid at Swepco Tube in New Jersey, his coworkers rescued him and suffered some injuries of their own
- An 8,000-gallon container of some sort of resin launched itself through the roofof a hot tub factory in California
- Three workers were sprayed with sodium nitrate at an Intel facility in Oregon
- 7,500 gal of hydrochloric acid spilled when a trailer exploded at a power plant in Missouri
- A malfunctioning flange cause a spill of 1,200 gal of sulfuric acid at Arcelor Mittal Steel in Ohio
- “Thousands of gallons of acid” spilled at Brenntag Pacific in Utah when workers were unloading a rail car and there was some sort OF “problem with the hose”
- A pump failure led to the release of phosphorus trichloride and hydrochloric acid at ICL America in Ohio
- Hydrogen cyanide was released at a Thomas & Betts factory in Canada; Thomas & Betts produces products for the electricity industry
- A man refining gold using electric heaters and “chromatic” (chromic?) acid in the back of a pickup truck triggered a hazmat response in California
Not covered: meth labs; ammonia leaks; incidents involving floor sealants, cleaning solutions, or pool chemicals; transportation spills; and fires from oil, natural gas, or other fuels.
The lab is a splash zone
The University of California, San Diego, has a great new video on eye protection. It was produced by the chemistry department’s Haim Weizman, who was also the man behind A day in the lab, To be (safe) or not to be, Flash chromatography 101, and a trio of videos on working with pyrophoric reagents and reactive metals.
Overall, I think the “splash zone” video is a terrific illustration of why it’s important to always wear eye protection in labs, even when you’re not the one handling the chemicals. That said, the safety glasses featured in the video are really designed for impact protection, not splashes. For splash protection, people really need to use goggles.
Friday chemical safety round-up
Chemical health and safety news from the past week:
- The National Science Teachers Association posted about Safety in the science lab
- The May issue of AIChE’s Process Safety Beacon focuses on mechanical integrity of tubing (pdf) and notes “Don’t forget about tubing just because it is usually small.” (lab scale chemists, pay attention!)
- California’s San Onofre nuclear plant may resume partial service in June. The shutdown is from problems with pipes leaking radioactive steam, but it turns out to be a mechanical rather than a chemical problem. According to the linked story, “The issue appears to be caused by the level of steam flow through the tubes, which causes certain longer tubes to vibrate and rub against each other.”
- A fire in March at New Jersey’s Sussex County Technical School turned out to be from zinc metal powder + wet paper towels in a trash can. “The fire caused heavy damage to the lab while seven other rooms, including four offices on the first floor, sustained smoke and water damage. The damage has been estimated at ‘over $500,000.’”
- Corden PharmaChem was fined $300,000 for a 2008 explosion that killed one worker and injured another at a plant in Ireland
- The University of Vermont was fined $19,660 for records violations relating to state hazardous waste regulations. “The inspector found that records of self-inspections in the sampled laboratories were not consistently maintained, that the records used for laboratory self-assessments were not those that are required, that some storage containers were mislabeled and that laboratories didn’t take adequate corrective actions after learning of violations.”
Fires and explosions:
- Fires in two reactors at a chemical plant in India killed four workers and injured an additional 15. “The blast was so big that it was easily heard even at a distance of 6 km, and so powerful that the pieces of reactors were found spread in fields up to a distance of 600 yards. The 50-kg cover of the reactor was also found nearly 300 yards away from the spot.”
- A fire at an Arizona Chemical plant in Florida started in a wastewater basin
- Diesel fuel ignited in a BNSF Rail Yard Chemical Testing Lab in Kansas when the ventilation system failed, resulting in a damage estimate of $75,000. There’s no mention in the story about what might have sparked the fire and whether the chemist doing the testing was injured.
- Some sort of explosion in a lab at New Zealand’s Canterbury University left two students with head and neck injuries
- “A small fire from a chemical reaction” burned one student at a high school in Wyoming
- Something involving silver nitrate flared up in a U.K. science classroom, burning a teacher on her hands and face
Leaks, spills, and other exposures:
- Butanol leaked at an Oxea plant in Texas
- A San Francisco VA Medical Center researcher died from infection by a bacterial strain he was studying, Neisseria meningitidis, which causes meningitis and septicemia. Added: ScienceInsider has some more details.
Not covered: meth labs; ammonia leaks; incidents involving floor sealants, cleaning solutions, or pool chemicals; transportation spills; and fires from oil, natural gas, or other fuels.
Moving forward at UCLA
With the news last month that the Los Angeles County Superior Court has once again delayed the arraignment of the University of California, Los Angeles, and chemistry professor Patrick Harran on felony charges for labor code violations, it seemed appropriate to take a closer look at what the university is doing to move forward.
In response to the death of UCLA laboratory researcher Sheharbano (Sheri) Sangji, the university instituted a number of safety improvements, including more thorough lab inspections, more flame-resistant lab coats, and additional special training in the use of safety gear and the handling of air-sensitive chemicals. UCLA also established a Center for Laboratory Safety (CLS). According to the CLS website, the center was created to “improve the practice of laboratory safety through the performance of scientific research and implementation of best safety practices in the laboratory.” The Center operates under the oversight of an advisory board, with technical support from the UCLA Office of Environment, Health & Safety (EH&S) and the UCLA School of Public Health’s Department of Environmental Health Sciences.
James Gibson, UCLA’s director of EH&S and the executive director of the CLS, has been on the road constantly promoting the center as well as UCLA’s overall response to the Sangji incident. Also promoting the center everywhere has been Erike Young, the EH&S director for UC’s Office of the President. Young is charged with seeing that all of the UC campuses improve their safety culture. He pointed out during his 2010 talk at the National Research Council’s Safety Summit that most UC campuses do not perform “lab safety inspections”, although they may be inspected by individual programs for fire safety, biological safety, radiation safety, etc. Audits commonly find lack of safety training by PIs and research teams, lack of enforcement on PPE requirements, insufficient or improper safety equipment, and lack of follow-up on inspections.
Young said that UC’s challenge is to integrate safety management into the basic operation of research laboratories, a concept also championed by the ACS Safety Culture Task Force (pdf). If structure drives behavior, then it stands to reason that laboratory safety issues will more frequently be apparent at facilities without a strong safety culture. Unfortunately, Young noted that university EH&S lab safety is largely regulatory driven, not risk based. This is something the CLS is trying to change.
So what has UCLA done to fundamentally change its safety culture? Among other things, the University has appointed a new chemical hygiene officer (CHO), Petros Yiannikouros.
I had the pleasure of spending a number of hours with Yiannikouros during the recent ACS meeting in San Diego. I found him engaging, communicative, and fun to talk with (which makes him one of my new best friends). A native of the island of Cyprus, Yiannikouros is at UCLA at least partly because of its proximity to the ocean – he told me it is impossible for him to live more than an hour from water and an opportunity to fish. Upon a little research, I find that his background also includes serving as the Head Scientist in charge of Quality Control for the Carlsberg Brewery in Cyprus!
While he was unable to speak to the Sangji incident (it precedes his time at UCLA), Yiannikouros outlined some of the challenges he faces. When asked what he believes makes a successful CHO, he stressed experience in the laboratory. Yiannikouros feels it is difficult, if not impossible, for a CHO to adequately manage safety in a research environment without clearly understanding the processes and procedures. With the emphasis at UCLA on the handling of reactive chemicals, Petros finds his experience in organic research to be invaluable, particularly in respect to the handling and use of organometallics.
The California Division of Occupational Safety & Health (Cal/OSHA) agrees with Yiannikouros. “A CHO should be able to interact with investigators as a peer and be able to understand what it is they’re talking about,” as well as know the various regulations involved, Cal/OSHA senior safety engineer Deborah Gold told my co-blogger Jyllian in 2010, when discussing why the agency felt a previous UCLA CHO was unqualified.
I certainly wish Yiannikouros luck at UCLA as he continues to help change the safety environment. It is clearly a challenge to get principal investigators to “buy in” to structured safety behavior, but it looks like Yiannikouros has the tools to do that at UCLA.
Dow and Minnesota team up on safety
Dow Chemical and the University of Minnesota (UMN) announced on Monday a pilot program to improve laboratory safety in the university’s chemistry and chemical engineering laboratories.
UMN is one of the universities benefiting from a program Dow announced last year in which the company is investing $25 million per year for 10 years in research programs at 11 academic institutions. The new safety program is independent of that effort but germinated in the relationship established between Dow and the university, says Frank S. Bates, head of UMN’s chemical engineering and materials science department.
The safety program also extends beyond research programs sponsored by Dow. Central to the effort is a Joint Safety Team (JST) made up of the safety officers from every chemistry and chemical engineering research group. “All of those safety officers will be interacting with Dow and working together to learn best safety practices” from the company, says William B. Tolman, chair of the chemistry department.
At a kick-off meeting a few weeks ago, representatives from Dow and the university agreed that their focus would be on building and sustaining a good safety culture. UMN already seems to have some good procedures and protocols in place, says Pankaj Gupta, senior strategy leader for research and development at Dow. The task is how to raise awareness of those and how to share Dow’s best practices and adapt them to a university setting.
To that end, in the next couple of weeks, Dow and UMN plan to survey chemistry and chemical engineering faculty, postdocs, and students to get their feedback on the current state of laboratory safety and what needs to be improved. Then the program will try to address those concerns by having Dow representatives visit the campus to work with members of the JST. Some or all JST members will also visit Dow, where they will be exposed to things like Dow’s training program, its laboratory audits, and how scientists approach experiments, Gupta says. Repeat surveys will help determine how the program progresses.
Gupta has already surveyed recently-hired Dow employees to get their input on the differences between academic and Dow safety culture. “The number one theme that came up again and again was awareness,” Gupta says, adding that other concerns included specifications for protective equipment, protocols, and pre-task analysis. “When our new employees come in, they spend about 30 hours in mandatory training before they can set foot in the lab to do an experiment,” providing an immediate lesson that safety comes first, Gupta says. Monthly safety meetings and pre-task analysis, in which peer groups discuss the hazards of new procedures and what to do if something goes wrong, also reinforce that safety is an integral part of laboratory experiments.
One of the things the pilot program will work on is creating an environment in which it is both expected and comfortable for people to raise questions and work with each other around hazard assessment, says Lori Seiler, associate director for environmental health and safety in research and development at Dow.
The pilot program will run through the summer. Then Dow and UMN will take stock of the effort and figure out how to proceed. Two UMN alumni now employed at Dow—one chemist and one chemical engineer—are on the core team working with the university.
Neither Dow nor UMN comes to the program with the expectation that the university will duplicate Dow’s safety program, Bates says. “But there’s a lot of room between what we’ve done in the past and what they do at Dow,” he says. “Our intention is to make things better in a university setting.”
Key to the effort is the JST, Tolman adds. “We decided early on that it would be actual students and postdocs who would lead the effort, since they’re the ones in the labs,” he says. And the interdepartmental nature of the team should strengthen it, by providing both a common goal and a wider range of experience.
The team should also help address the problem of high turnover in academic labs, Tolman says. Even as some JST members leave every year, their replacements will learn from and be supported by veteran members. And if the safety officers are trained well, they in turn will do a better job of training new research group members, Tolman says.
“My own safety officer from my group came in my office two days ago and she told me flat-out, ‘This is going to make my job easier,’” Bates adds. He hopes that the JST will add some professionalism to the safety officers and promote their authority in the research groups they serve. “And to have a partner at Dow who they can consult with and make contact with occasionally as a resource? That’s just fantastic,” Bates says.
Bates and Tolman say that their faculty members are enthusiastic about the program, even though it means a big time commitment for the safety officers. “We agree it takes time, but it needs to take time. This is important and a high priority for us,” Tolman says.
And although the safety officers may have some busy weeks ahead, in six months or a year from now, “it’s not going to take any more time. I think it will take less time and less concern on the part of the safety officers,” Bates says.
Friday chemical safety round-up
Chemical health and safety news from the past week:
- Theo Gray learned why glove compatibility is important:
As the toluene evaporated, the white phosphorus did what its name implies—it phosphoresced, reacting with oxygen from the air to produce a luminous gas fractions of an inch above the surface of my hand. This reaction is not just risky to create, it’s also difficult to photograph. We used the best low-light camera available to get it to show up so well.
To the dark-adapted human eye, though, it looks bright, and frankly rather alarming, especially when I took the gloves off and realized that toluene goes through latex.
- Dogs accidentally poison veterinarians: rodenticide zinc phosphide + stomach acid + induced vomiting = phosphine gas in the clinic
- U.S. Secretary of Labor Hilda Solis mentioned Sheri Sangji in a piece for Workers Memorial Day (April 28)
- Poor safety record no bar to winning government construction contracts
Fires and explosions:
- An explosion at a Mitsui Chemicals plant in Japan killed one and injured 11 workers
- A broken elbow joint led to molten glas sspilling at a Johns Manville facility in Indiana; “the glass spread throughout the building and threatened to destroy the structure”
- A teacher and three students were burned in a fire in a New York middle school science class; the demonstration involved–yes, you guessed it–methanol
Leaks, spills, and other exposures:
- Roughly 53 liters of toluene spilled in an industrial park in Calgary, Canada
- The University of Virginia chemistry department got a visit from fire and hazmat crews over venting (liquid?) nitrogen tanks
Not covered: meth labs; ammonia leaks; incidents involving floor sealants, cleaning solutions, or pool chemicals; transportation spills; and fires from oil, natural gas, or other fuels.
Friday chemical safety round-up
Chemical health and safety news from the past week:
- Chemjobber discussed electrostatics and glass-lined reactors
- It’s the Rheo Thing posted about rubber glove safety and the general role of safety officers
- The Chemical Safety Board released its report and video on a 2010 explosion at a DuPont plant in New York that killed one worker and injured another; CSB found that welding on the roof of an empty polyvinylfluoride slurry storage tank ignited vapor that DuPont workers didn’t believe would be in there and didn’t test for; earlier in 2010, CSB had issued a safety bulletin on the dangers of “hot work” (pdf), or “activities with the potential to create a source of ignition”
- Destroying the U.S. stockpile of chemical weapons will take an extra two years and $2 billion
- Massachusetts town eyes new requirements for General Chemical as hazardous waste facility prepares to close
- Neighborhoods near former lead factories show hazardous levels of lead in soil
- EPA issued fracking emissions rules
- Chemists discovered a new colorful detector for phosgene
Fires and explosions:
- A fire at 3F Fluorochemical, in China’s Inner Mongolia region, started when tanks of “VDF” (vinylidene fluoride?) gas caught fire and exploded; three worders were injured
- A fire at India’s Physical Research Laboratory started in an waste storage area
Leaks, spills, and other exposures:
- Boron trifluoride leaked from a cylinder being shipped from Idaho National Laboratory to a nuclear reactor
- Formalin spilled when a worker dropped a container at a medical center in Massachusetts, a Canadian hospital had a formaldehyde spill, and hydrochloric acid spilled at a dental lab in North Dakota
- Two students passed out in a lab involving ethanol and food coloring at Baylor University
- Radioactivity detected in a University of Memphis scrap metal dumpster turned out to be from an old “metal door apparatus” that contained naturally radioactive materials
Not covered: meth labs; ammonia leaks; incidents involving floor sealants, cleaning solutions, or pool chemicals; transportation spills; and fires from oil, natural gas, or other fuels.
Historical accidents at Caltech, via Linus Pauling’s notebooks
Via frequent commenter qvxb, Oregon State University has scans of the lab notebooks of alumnus Linus Pauling available online, and they include descriptions of at least two lab accidents at Caltech.
One, on August 10, 1939, was an ether explosion:
Today, at about 8:30 am, Mr. Leo Brewer (on appointment as assistant for the summer at $40 a month) was preparing absolute ether in Room 351 (large organic lab.) and had an explosion. He had 40 liters of ether there. The explosion blew out all the windows and wrecked the hoods and chemical desks in the room, and caused some damage in adjoining rooms. Brewer was burned slightly. Total damage to laboratory and equipment about $14000.00
Brewer told me that he and Shei were wiping up some ether that he had spilled, and had wiped it all up when the explosion occurred. No flames were about (he used steam for the distillation). The source of fire is unknown. Shei had just stepped out into the hallway when the explosion occurred.
Koepfli heard the explosion at his home, nearly a mile away.
Another, on Thursday, Sept. 23, 1943, involved a fatal exposure to ethylchloroformate:
Shortly after 1 pm Mrs Elizabeth Swingle, Crellin Stockroom Keeper, was showered wtih ethylchlorocarbonate (ethylchloroformate, C2H5OCOCl) in the sub-basement near the elevator, perhaps because of pressure in the bottle, which contained CaCO3 as stabilizer. [William] Lipscomb heard her call, and took her under shower (cold water) in 058. Miss Rooke and Swingle, Lipscomb, Trueblood treated her with sodium bicarbonate, removed clothes, and showered her again. Lucas had ammonia put on the floor. The Pasadena Fire Dept Truck (Captain Baker) pumped air out. I arrived at 3 pm – Col. Wyman and Dr. Koepfli were in charge. At 4 pm subbasement was clear, and I dismissed the trucks. I had been at home – reached lab at 3:15.
Koepfli told Miss Rooke, Lipscomb, David Shoemaker, and Trueblood to lie down and call the doctor if any symptoms develop.
Koepfli will make a report on the accident.
Mrs. Swingle is in the Huntington Hospital, under care of Dr. Kremers.
—–
Sept. 24, 1943. Mrs. Swingle died last night, after about 8 hours.At 4 pm Koepfli told Dr. Kremers over the phone, in my hearing, that the treatment should be as for phosgene.
According to an obituary, Elizabeth Swingle had trained as a bacteriologist and was the wife of chemist Stanley Swingle.
Lab accidents aside, I could probably spend days poking around Pauling’s notebooks. If any Safety Zone readers take the time to do so themselves, report back what you found most interesting!
Friday chemical safety round-up
Chemical health and safety news from the past week:
- It’s the Rheo Thing reflected further on a possibly chemophobic grant reviewer: Poorly posed concerns about chemical safety
- Lab coat art appeared at Pittcon
- The Chemical Safety Board will hold a public meeting on April 19 in Buffalo, NY, to present its findings in an investigation into an explosion involving a welder and a vinyl fluoride tank at a DuPont plant
Fires and explosions:
- A fire in a tank at RPM Wood Finishes Group in North Carolina injured one worker; the company makes wood and industrial metal finishing coatings
- A lithium battery explosion at a General Motors plant in Michigan injured two employees; “The explosion occurred during extreme testing of an experimental battery in a test chamber at the Alternative Energy Center laboratory” and “‘Chemical gases from the battery cells were released and ignited in the enclosed chamber,’ GM said. ‘The battery itself was intact.’”
- At a Mercury Marine plant in Wisconsin, “employees poured alloy-melted molten aluminum” and then “melted aluminum shot 25 feet to the ceiling and ignited fine dust particles, which then drafted into the exhaust system”; no one was injured
- Sodium chlorite burst into flame when it was being repackaged at NW Chemical Recycling in Washington; the fire led to the discovery of two old trucks containing more than 3,000 chemical containers containing mercury, mildly radioactive uranium, and sodium metal, among other things
- “Excessive gas” in a chemical tank blew off the top and caused a fire in Pakistan
- A methanol fire in a chemistry classroom injured a student at a Hawaii high school
Leaks, spills, and other exposures:
- Gallium trichloride fumes were released at metal products manufacturer 5NPlus in Connecticut
- Methyl bromide leaked when workers were using it to fumigate a Graincorp Carrington terminal in Australia
- A University of Cincinnati graduate student was reportedly injured in “a toxic chemical explosion” while etching aluminum alone at 1 a.m.; here’s the university’s description of the event (the moral, as usual: wear your PPE!):
UCPD and CFD were dispatched to ERC shortly before 1AM today for a chemical spill. A grad student working with acid (to etch aluminum) had spilled about ½ liter. The researcher was using PPE, but believed they may have gotten some acid on their arms when they removed the PPE. They were examined and released at University Hospital. The building was evacuated while the Fire Dept. evaluated the situation and then re-occupied when it was determined there was no risk to others in the building. EH&S was notified and responded in to handle the clean-up.
- A capsule labeled “sarin” was discovered in western Russia
Not covered: meth labs; ammonia leaks; incidents involving floor sealants, cleaning solutions, or pool chemicals; transportation spills; and fires from oil, natural gas, or other fuels.
UCLA, Harran arraignment deferred yet again in Sheri Sangji case
The University of California, Los Angeles, and chemistry professor Patrick Harran were scheduled to be arraigned this afternoon on felony charges for violating California labor laws, but the court proceeding has once again been postponed. The charges stem from the death of researcher Sheharbano (Sheri) Sangji three years ago after a fire in Harran’s lab. Arraignment is now scheduled for June 7, reports C&EN SCENE editor Michael Torrice.
As in past hearings, the delay came at the request of the defense. Torrice adds that the judge indicated that this delay would be the last. Arraignment was already put off three times for the university and twice for Harran.
Sangji’s sister, Naveen Sangji, attended the hearing today and says that a preliminary plea deal was offered to the defendants on Monday. Supreme Court Justice Anthony Kennedy said in recent opinions that plea bargains are now so central to the justice system that “criminal justice today is for the most part a system of pleas, not a system of trials,” adding that “ninety-seven percent of federal convictions and ninety-four percent of state convictions are the result of guilty pleas” (federal statistics source, state statistics source, via NPR).
ETA: The Los Angeles Time story from today’s hearing says that “Judge Shelly Torrealba ordered professor Patrick Harran and lawyers for the regents back into court June 7, effectively setting a deadline for them to reach a plea agreement with prosecutors.” Here are the judge’s exact words, per C&EN’s Torrice:
My understanding is the request at this time of the parties is to continue the arraignment one last time, as I understand it, to June 7. We will then proceed with arraignment at that time. Is that the request of the parties?
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